Crystal engineering of an nbo topology metal-organic framework for chemical fixation of CO2 under ambient conditions.
نویسندگان
چکیده
Crystal engineering of the nbo metal-organic framework (MOF) platform MOF-505 with a custom-designed azamacrocycle ligand (1,4,7,10-tetrazazcyclododecane-N,N',N'',N'''-tetra-p-methylbenzoic acid) leads to a high density of well-oriented Lewis active sites within the cuboctahedral cage in MMCF-2, [Cu2(Cu-tactmb)(H2O)3(NO3)2]. This MOF demonstrates high catalytic activity for the chemical fixation of CO2 into cyclic carbonates at room temperature under 1 atm pressure.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 53 10 شماره
صفحات -
تاریخ انتشار 2014